Genesis of S-type Granites in the Pengshan Sn-polymetallic Ore Field, Northern Jiangxi Province and its Implications

The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block, spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift, and on one side of the MLYDZ. The studies of LA–ICP–MS zircon U–Pb chronology and petrogeochemistry for Early Cretaceous acid granites from the Pengshan ore field were carried out in this paper. We report zircon U–Pb geochronology and whole-rock geochemistry for acid granites in the Pengshan ore field. The zircon U–Pb ages of the muscovite-granite, biotite adamellite and granite-porphyry are 127.6 ± 1.7 Ma, 126.9 ± 1.6 Ma and 126.6 ± 2.0 Ma, respectively. The granites in Pengshan are characterized by a high silicon content and are rich in alkali. They belong to high-potassium, calc-alkaline, peraluminous granite. The rocks have a relatively high Rb/Ba ratio, and the data points for muscovite-granite and biotite adamellite all fall within the clay-rich sources region, near the pelite-derived end-member, showing that the Pengshan muscovite-granite and biotite adamellite mainly originated from the partial melting of metapelites with high maturity. The transformation of the compressional and extensional tectonics in this region approximately 128 Ma obviously lags behind that in the mid-segment of the Jiangnan Uplift (135 Ma), but occurred earlier than the MLYDZ (126 Ma). The Pengshan ore field extends from the mid-segment of the Jiangnan Uplift to the MLYDZ. Although the tectonic stress field is constrained by the combination of the two secondary tectonic units, the time of tectonic system transformation is closer to the MLYDZ because the spatial orientation of the area is enclosed in the MLYDZ. Relevant geophysical and drilling data confirm the rationality of Pengshan–Ao’xia as a multi-center vertical zoning ore field, and show the scientificity of the prospecting idea of abutting joint between the north-west of Pengshan area and the south-east of Ao’xia area.     

The cumulative characteristics of PAEs in PM2.5 in Changji,Northwest China

ABSTRACT

This paper discusses characteristics of the seasonal variation in phthalate acid esters (PAEs) in the PM_2.5 in the city of Changji, which is located an arid area of Xinjiang Province, northwest China. Samples were collected using a Laoying 2030 median discharge intelligent total suspended particulate (TSP) sampler and analyzed by a Shimadzu GC-2010 gas chromatograph. The results showed that PAEs in PM_2.5 were mainly composed of phthalic acid dibutyl phthalate (DBP) and phthalic acid (2-)ethyl hexyl ester (DEHP). DBP and DEHP are the most commonly used plasticizers, accounting for the majority of plasticizers used, and have large environmental emissions. Compared with the proportions of TSPs, proportions of DBP and DEHP in the PM_2.5 were lower, while the proportions of DMP and DEP were higher. A correlation exists between the distribution of PAEs and the particle size and concentration of atmospheric particulates. Seasonal variations in DBP and DEHP were the same, with lowest concentrations in the summer. Although seasonal variation in DMP was not the same as those of DBP and DEHP, the general trend was similar. Seasonal variation in DEP was different from those of other PAEs. This pattern is related to PAE characteristics and seasonal variations in their sources.     

Does geographic distance have a significant impact on enterprise financing costs?

Journal of Geographical Sciences - As information technology has been applied more broadly and transportation infrastructure has improved, persistent debate has existed as to the question of...     

开挖前降水引发基坑变形机制模型试验研究

现有基坑相关研究主要关注土方开挖过程引起的变形，认为围护结构变形起点是土方第1次开挖。然而，一些工程实测表明，基坑开挖前降水阶段即可引起围护结构及周边地层发生厘米级的变形。显然，未考虑开挖前变形的基坑监测数据将低估基坑施工的环境效应。为了研究基坑开挖前降水引发基坑变形的机制，开展了室内模型试验，对基坑开挖前降水过程进行了缩尺精细化模拟。通过微型降水井的设置与调控，模型试验真实再现了实际基坑降水过程中井流效应对围护结构受力变形的影响。试验过程中发现，随着降水的进行，坑外降水漏斗不断扩展，围护结构悬臂式侧移及坑外拱肩式地面沉降也随之产生。另外，降水导致墙前水压力明显减小，并诱发墙前侧向总压力重分布（以减小为主），围护结构为此发生指向坑内的悬臂式运动以寻求新的受力平衡，并通过墙后土体损失诱发坑外地层变形。     

基于混合聚类的岩体结构面优势分组方法

提出一种基于凝聚层次法和模糊C均值法的混合聚类法,用于对岩体结构面的优势组划分。该方法将结构面投放到在单位球面上,并使用欧式距离作为极点的相似性度量准则。先剔除结构面数据中的孤值产状,然后用凝聚层次法得到初步聚类结果,并将其作为FCM法的初始聚类中心,最后用FCM法划分优势组。通对人工生成产状样本的分组,验证了该法的正确性。将该方法应用于大藤峡坝址区实测的结构面数据的划分。在实测数据中寻找到两个孤值产状,成功将大藤峡D1y^1-3地层岩体结构面划分为两组,得到了符合实际的分组结果。     

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.     

辽宁沿海地区海洋经济增长质量空间特征及影响要素

在海洋经济质量转型之期,基于“认知—评价—建构—优化”理念,界定海洋经济增长质量内涵,通过中心-引力模型评价分析2000—2014年辽宁沿海地区海洋经济增长质量空间特征,构建了海洋经济增长质量模型,识别影响其空间特征的相关要素,并根据要素作用程度提出优化建议。研究发现：① 辽宁沿海地区海洋经济增长质量呈“核心—圈层”结构,形成以大连为“领头雁”的雁阵式相互继起模式;“钻石型”引力流结构促成辽宁沿海地区集中化连片发展格局;② 海洋经济增长质量空间特征主要受空间集聚效应影响,海洋资本、海洋基建和海洋产业结构成为推动海洋经济增长质量循环引力流的顺流机制,其中海洋产业结构成为影响辽宁海洋经济增长质量圈层空间集聚效应的关键流;海洋人才成为制约海洋经济增长质量循环引力流的逆流机制;③ 通过路径作用程度的象限划分,提出强化大连中心地职能,针对腹地城市定位及资源禀赋条件提出调控措施,推进沿海区域协调与一体化进程。     

榍石LA-SF-ICP-MS U-Pb定年及对结晶和封闭温度的指示

榍石富含U、Th，贫Pb，是U-Pb定年的理想矿物之一。本文采用激光剥蚀-高分辨等离子体质谱建立榍石U-Pb定年方法，采用25~30μm激光斑束，准确测定榍石U-Pb标准样品BLR-1（~1048Ma）、OLT-1（~1014Ma）和Pakistan（~21.4Ma），以及年轻榍石样品（<100Ma）U-Pb年龄，提高了检测准确性和空间分辨率。综合对比共生锆石和榍石U-Pb年龄、榍石颗粒微量元素和U-Pb年龄环带及不同成分岩浆岩（SiO₂含量48.1%~77.0%）中岩浆榍石的结晶温度，结果表明：岩浆演化过程中，榍石具有宽泛的结晶温度（600~900℃，峰值~750℃），主要集中于岩浆演化中晚期结晶，榍石U-Pb同位素封闭温度接近或略低于锆石，因此同一岩浆体系中锆石与榍石的年龄差异可能反映了该熔体较晚达到榍石饱和，而非熔体热演化历史或封闭温度信息。     

利用卫星遥感海面温度、高度联合反演南海北部三维温度场

利用历史观测得到的温度剖面数据,通过严格筛选和插值,建立了南海北部的气候态垂向温度剖面。随后,利用回归统计分析的方法构建了海面温度异常(SSTA)、海面高度异常(SSHA)联合扩展温度剖面的经验回归模型,并采用卫星遥感得到的SST和SSH数据扩展了南海北部的三维海洋温度场,其时间分辨率为天,空间分辨率为0.25°×0.25°。通过与观测数据的对比研究,扩展得到的温度场可以较为准确地反映南海北部温度剖面的结构特征,并且能有效地体现出一些中尺度变化过程。结果表明,本研究反演得到的三维温度扩展场是较为可靠的,它可以作为海洋数值模型的初始场,实现现场观测数据和卫星遥感数据的互补,有助于更好地分析南海北部温度场的三维结构及变化特征。     

碳氮稳定同位素比值在潮间带大型底栖动物组织间差异性研究

近年来，稳定同位素技术已被广泛应用于食物网研究中。然而，生物样品取样部位对食物网构建的影响的研究相对少见。大型底栖动物作为潮间带食物网的重要组成部分，在食物网研究中有必要对其采样部位进行统一，以增加研究结果的准确性及可比较性。本研究选取黄河三角洲和烟台潮间带10种代表性的大型底栖动物，比较δ13C和δ15N在不同采样部位中的差异。结果显示，对于大多数底栖动物而言，采样部位将直接影响到δ13C和δ15N的测定结果。当底栖动物作为摄食者，需分析其食性和营养级时，应统一采用肌肉组织，如贝类的闭壳肌或足部肌肉，蟹类的鳌足肌肉，鱼类的背部肌肉；当底栖动物作为被摄食者，需分析次级消费者的食性和营养级时，除多毛类采用去除消化道内容物的体壁外，其他种类应选取整体（难以被消化的组织除外），如贝类的软体部，蟹类肌肉与鳃等的混合组织。